202402071059 Solution to 1980-CE-PHY-II-16

A light ray passes through a spherical air bubble in water. Which of the following represents the path of the emergent ray?

A. P
B. Q
C. R
D. S


Roughwork.

Refractive (/refraction) index of a pure substance, with some exceptions, is proportional to its density; and of a mixture of substances, as a rule, to its mass concentration.

Thus water, higher in density than air, should have a larger refractive index than air:

n_{\textrm{water}}>n_{\textrm{air}};

alternatively, as light travels in air faster than in water, from

\displaystyle{v=\frac{c}{n}},

it can be seen also.

Let \theta_{1} and \theta_{2} be the angle of incidence and of refraction when light is refracted through the first interface; and \theta_{2} and \theta_{3}, when through the second interface.

Assuming WLOG n_1\geqslant n_2 and noting \sin \theta \geqslant 0 (non-negative) for \theta\in \big[ 0,\frac{\pi}{2}\big]. By Snell’s Law, write

\begin{aligned} n_1\sin\theta_1 & = n_2\sin\theta_2 \\ \frac{\sin\theta_1}{\sin\theta_2} & = \frac{n_2}{n_1}\leqslant 1 \\ \sin\theta_1 & \leqslant \sin\theta_2 \\ \theta_1 & \leqslant \theta_2 \\ \end{aligned}

\therefore \quad n_1\geqslant n_2\Longrightarrow \theta_2\geqslant \theta_1

\therefore\quad n_{\textrm{water}}>n_{\textrm{air}}\Longrightarrow \theta_{\textrm{air}}>\theta_{\textrm{water}}

Answer. Path P.

Reverse the direction of incidence and emergence:

Light ray along path: P bends away from and then towards the normal; Q bends towards the normal once and again; R bends away from the normal once and again; S bends towards and then away from the normal. Wits have it that Q and R are unlikely. So we turn our attention to light rays P and S.

Fussy enough, path P is symmetric with respect to straight line L_P; but there across path S is no line of symmetry were it to be L_S.


This problem is not to be attempted.

202312201537 Solution to 1980-CE-PHY-II-13

6\times 10^{-3}\,\mathrm{m^3} of a gas is contained in a vessel at 91^\circ\mathrm{C} and a pressure of 4\times 10^5\,\mathrm{Pa}. If the density of the gas at s.t.p. (0^\circ\mathrm{C} and 10^5\,\mathrm{Pa}) is 1.2\,\mathrm{kg\, m^{-3}}, what is the mass of the gas?

A. 7.2\,\mathrm{g}
B. 14.4\,\mathrm{g}
C. 21.6\,\mathrm{g}
D. 28.8\,\mathrm{g}

Official answer: C


Roughwork.

\textrm{\textbf{\scriptsize{CASE I}}} (closed vessel)

Assumed a closed vessel, its volume V=\textrm{Const.} a constant. Then, that 6\times 10^{-3}\,\mathrm{m^3} of gas fully occupied the closed vessel, implies that the volume of the vessel is also

V=6\times 10^{-3}\,\mathrm{m^3}.

Hence may we write

\begin{aligned} \textrm{density }(\rho ) & = \frac{\textrm{mass }(m)}{\textrm{volume }(V)} \\ m & = \rho V \\ & = (1.2\,\mathrm{kg\,m^{-3}})(6\times 10^{-3}\,\mathrm{m^3}) \\ & = 7.2\,\mathrm{g} \\ \end{aligned}

And we get option A, which is different from the official answer C. Hence, we need to look into

\textrm{\textbf{\scriptsize{CASE II}}} (open vessel)

We set up the background below.

******************

1. Ideal gas law:

An ideal gas satisfies the general gas equation

pV=nRT

where p, V, n, R, and T are the pressure, the volume, the amount of substance (/number of moles), the ideal (/universal) gas constant, and the temperature of the gas.

2. Conversion of scales of temperature:

x\,^\circ\mathrm{C} \approx (x+273)\,\mathrm{K}

3. Relationship between chemical amount (/number of moles) n, total mass m, and molar mass M, of a substance.

\displaystyle{n=\frac{m}{M}}

Note that total mass m and number of moles n are extensive (/extrinsic) properties; whereas molar mass M is an intensive (/intrinsic) property.

******************

At the start t=t_0,

\begin{aligned} p(t_0) & = 4\times 10^5\,\mathrm{Pa} \\ V(t_0) & = 6\times 10^{-3}\,\mathrm{m^3} \\ T(t_0) & = 364\,\mathrm{K} \\ R & = 8.31\mathrm{m^3\,Pa\,K^{-1}\,mol^{-1}} \\ \end{aligned}

substituting,

\begin{aligned} p(t_0)V(t_0) & = n(t_0)RT(t_0) \\ (4\times 10^5)(6\times 10^{-3}) & = n(t_0)(8.31)(364) \\ n(t_0) & = 0.7722\,\mathrm{mol}\quad\mathrm{(4\, s.f.)}\\ \end{aligned}

at some point later t=t_{1} the gas in standard temperature and pressure (s.t.p.),

\begin{aligned} p(t_1) & = 10^5\,\mathrm{Pa} \\ V(t_1) & = 6\times 10^{-3}\,\mathrm{m^3} \\ T(t_1) & = 273\,\mathrm{K} \\ R & = 8.31\mathrm{m^3\,Pa\,K^{-1}\,mol^{-1}} \\ \end{aligned}

substituting,

\begin{aligned} p(t_1)V(t_1) & = n(t_1)RT(t_1) \\ (10^5)(6\times 10^{-3}) & = n(t_1)(8.31)(273) \\ n(t_1) & = 0.2645\,\mathrm{mol}\quad\mathrm{(4\, s.f.)}\\ \end{aligned}

From n(t_1)<n(t_0), it can be inferred that some portion of the gas was leaking from the open vessel to the atmosphere throughout the experiment.

\begin{aligned} \frac{m(t_1)}{n(t_1)} & = \frac{m(t_0)}{n(t_0)} = M \\ m(t_1) & = \bigg(\frac{n(t_1)}{n(t_0)}\bigg) m(t_0) \\ & = \bigg(\frac{0.2645}{0.7722}\bigg) m(t_0) \\ m(t_1) & = 0.3425m(t_0) \\ \end{aligned}

Provided \rho (t_1)=1.2\,\mathrm{kg\,m^{-3}}, we know

\begin{aligned} \rho (t_1) & = \frac{m(t_1)}{V(t_1)} \\ \rho (t_1) & = \frac{Mn(t_1)}{V(t_1)} \\ 1.2 & = \frac{0.2645M}{6\times 10^{-3}} \\ M & = 0.0272212\,\mathrm{kg\,mol^{-1}}\\ \end{aligned}

Hence

\begin{aligned} m(t_1) & =Mn(t_1) \\ & = (0.0272212)(0.2645) \\ & = 0.0072000074\,\mathrm{kg} \\ & = 7.2\,\mathrm{g} \\ \end{aligned}

And we get option A again, which is far from the official answer C.


Neither \textrm{\textbf{\scriptsize{CASE I}}} nor \textrm{\textbf{\scriptsize{CASE II}}} gives option C; have I actually made a circular argument?

Circular reasoning is a logical fallacy in which the reasoner begins with what they are trying to end with.

Wikipedia on Circular reasoning

Have I really?


No, just that you do so in the way than intended.

201907251758 Solution to 1980-CE-PHY-II-5

The kinetic energy E_\mathrm{k} of an object of mass m and speed v is given by the formula

E_\mathrm{k}=\displaystyle{\frac{1}{2}}mv^2.

In the situation that the object is thrown upwards with initial speed u, and subjected only to gravity \mathbf{g}, it can be expected that after some time of flight T, the object will return to its initial position, its downward speed in which is equal to the initial upward speed u.

Define a piecewise scalar function v(t) of time t:

v(t) = \begin{cases}  u-gt & \quad \textrm{when }0\leq t\leq \displaystyle{\frac{T}{2}} \\  -u+gt & \quad \textrm{when } \displaystyle{\frac{T}{2}}\leq t\leq T \end{cases}

or simply

v:[0,T]\subset \mathbb{R} \rightarrow [0,u]\subset \mathbb{R} given by t\mapsto \big|u-g(T-t)\big|.

Then

\begin{aligned} v^2 & =(u-gt)^2\quad \big( =(-u+gt)^2\big) \\ & = u^2-2ugt+g^2t^2 \quad \big(\forall\, t\in [0,T] \big) \end{aligned}.

Thus the kinetic energy E_\mathrm{k}(t) is

\begin{aligned} E_\mathrm{k}(t) & =\displaystyle{\frac{1}{2}}m(u^2-2ugt+g^2t^2) \\ & = \bigg( \displaystyle{\frac{1}{2}}mg^2 \bigg) t^2 + ( -mug ) t + \bigg( \displaystyle{\frac{1}{2}}mu^2 \bigg) \end{aligned}

where m, u, g are constants.

The kinetic energy E_\mathrm{k}(t) is set to zero at time t':

\begin{aligned} t' & = \displaystyle{\frac{-(-mug)\pm\sqrt{\big( -mug\big)^2-4\big(\frac{1}{2}mg^2\big)\big(\frac{1}{2}mu^2\big)}}{2\big(\frac{1}{2}mg^2\big)}} \\ & = \displaystyle{\frac{mug\pm\sqrt{m^2u^2g^2-m^2u^2g^2}}{mg^2}} \\ & =\displaystyle{\frac{u}{g}} \end{aligned}

Substituting t'=\displaystyle{\frac{u}{g}} for t in v=u-gt:

v=u-g\bigg( \displaystyle{\frac{u}{g}} \bigg) =0,

as checked.

And the answer is B.