Test each of the following differentials to see whether they are exact, using two methods for each:
(a)
,
(b)
,
(c)
,
(d)
,
(e)
.
K. S. Stowe. (2007). An Introduction to Thermodynamics and Statistical Mechanics
Revision.
(exact differentials)
The differential of a function is given by Eq. (5.8):
.
Therefore, one way to determine whether a differential given by Eq. (5.9):
is exact is to see whether we can find some function such that
.
If we can, the differential is exact, and if we can’t, it is inexact. Alternatively, we can use the identity
.
Combining this with equations (5.8) and (5.9), we can see that for exact differentials, Eq. (5.10):
.
Text on pg. 89, Sec. E, Ch. 5
Roughwork.
(a)
We can see that this is indeed an exact differential of the function
,
because
.
Or we can use Eq. (5.10). For this example and
, so
.
The two are the same, so the differential is exact.
Parts (b)
to (e)
are left to the reader as an exercise. Cf. analytic functions et Cauchy-Riemann equations.